Dichlorido(4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)gold(III) tetrachloridoaurate(III)
نویسندگان
چکیده
In the cation of the title compound, [AuCl(2)(C(24)H(16)N(2))][AuCl(4)], the Au(III) atom is four-coordinated in a distorted square-planar configuration by two N atoms from a 4,7-diphenyl-1,10-phenanthroline ligand and two terminal Cl atoms. In the anion, the Au(III) atom has a square-planar coordination. In the crystal structure, intra- and inter-molecular C-H⋯Cl hydrogen bonds are found.
منابع مشابه
Dichlorido(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)mercury(II) acetonitrile hemisolvate
The asymmetric unit of the title compound, [HgCl(2)(C(26)H(20)N(2))]·0.5CH(3)CN, contains two crystallographic-ally independent [HgCl(2)(C(26)H(20)N(2))] mol-ecules and one acetonitrile solvent mol-ecule. The Hg(II) atoms are four-coordin-ated in distorted tetra-hedral configurations by two N atoms from 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligands and two Cl atoms. The ligand ring syst...
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In the title compound, [Sn(CH(3))(2)(NSC)(2)(C(24)H(16)N(2))], a 1:1 adduct of dimethyl-tin diisothio-cyanate with 4,7-diphenyl-1,10-phenanthroline, the Sn(IV) atom shows a slightly distorted octa-hedral SnC(2)N(4) coordination. The methyl groups are trans to each other in the octa-hedron surrounding the metal atom [C-Sn-C = 176.61 (12)°].
متن کامل(4,7-Diphenyl-1,10-phenanthroline-κ2 N,N′)diiodidomercury(II)
In the mol-ecule of the title compound, [HgI(2)(C(24)H(16)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the bidentate 4,7-diphenyl-1,10-phenanthroline and two iodide ligands. There is a π-π contact between the pyridine and phenyl rings [centroid-to-centroid distance = 4.2387 (4) Å].
متن کامل2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin-1-ium tetrachloridoaurate(III)
Both the cation and anion of the title compound, (C(26)H(21)N(2))[AuCl(4)], are disposed about a plane of mirror symmetry. The 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolinium ring is oriented at a dihedral angle of 44.2 (1)° with respect to the planar phenyl ring systems. The Au(III) atom has a square-planar environment defined by four Cl atoms. The crystal structure is stabilized by C-H⋯π and ...
متن کاملtrans-Bis(4,7-diphenyl-1,10-phenanthroline-κ2 N,N′)bis(nitrato-κ2 O,O′)zinc(II)
The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn-O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C(2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a ...
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